Skip to main content

CDL Hazmat Endorsement Exam

Hazmat Classes Practice Questions

35 practice questions with detailed explanations — aligned to the CDL Hazmat Endorsement Exam.

  1. Q1.Hazard Class 1 materials are defined as:

    A.Gases
    B.Explosives
    C.Flammable Liquids
    D.Corrosives
    BExplosives

    Explanation: Class 1 consists of Explosives, divided into six divisions (1.1 through 1.6) based on their hazard level.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  2. Q2.Which Division of Class 1 explosives presents a 'Mass Explosion' hazard?

    A.Division 1.1
    B.Division 1.4
    C.Division 1.5
    D.Division 1.3
    ADivision 1.1

    Explanation: Division 1.1 explosives (like dynamite) have a mass explosion hazard, meaning the entire load could explode virtually instantaneously.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  3. Q3.Hazard Class 2 is comprised of:

    A.Gases
    B.Flammable Solids
    C.Oxidizers
    D.Radioactive materials
    AGases

    Explanation: Class 2 covers Gases, including flammable (2.1), non-flammable/non-poisonous (2.2), and poison gases (2.3).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  4. Q4.Propane is an example of which Hazard Class and Division?

    A.Class 3
    B.Division 2.1
    C.Division 2.2
    D.Class 4.1
    BDivision 2.1

    Explanation: Propane is a Flammable Gas, which falls under Class 2, Division 2.1.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  5. Q5.What defines a Class 3 material?

    A.Flammable and Combustible Liquids
    B.Flammable Solids
    C.Oxidizers
    D.Corrosives
    AFlammable and Combustible Liquids

    Explanation: Class 3 includes Flammable Liquids (flash point <140°F) and Combustible Liquids (flash point >140°F but <200°F).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  6. Q6.Gasoline is classified as:

    A.Class 2.1 (Flammable Gas)
    B.Class 3 (Flammable Liquid)
    C.Class 4.1 (Flammable Solid)
    D.Class 9 (Miscellaneous)
    BClass 3 (Flammable Liquid)

    Explanation: Gasoline is a liquid with a low flash point, making it a Class 3 Flammable Liquid.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  7. Q7.Which Hazard Class contains 'Flammable Solids'?

    A.Class 2
    B.Class 3
    C.Class 4
    D.Class 5
    CClass 4

    Explanation: Class 4 covers Flammable Solids (4.1), Spontaneously Combustible (4.2), and Dangerous When Wet (4.3).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  8. Q8.Materials that catch fire spontaneously upon contact with air are in which Division?

    A.Division 4.1
    B.Division 4.2
    C.Division 4.3
    D.Division 5.1
    BDivision 4.2

    Explanation: Division 4.2 consists of Spontaneously Combustible materials (pyrophoric) that ignite without an external ignition source within 5 minutes of contact with air.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  9. Q9.Division 4.3 materials are dangerous when:

    A.Exposed to air
    B.Exposed to heat
    C.Wet
    D.Compressed
    CWet

    Explanation: Division 4.3 is 'Dangerous When Wet'. These materials emit flammable or toxic gases upon contact with water.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  10. Q10.What is the primary hazard of Class 5 materials?

    A.They are explosive
    B.They yield oxygen, causing or enhancing the combustion of other materials
    C.They are poisonous
    D.They are radioactive
    BThey yield oxygen, causing or enhancing the combustion of other materials

    Explanation: Class 5 (Oxidizers and Organic Peroxides) releases oxygen, which intensifies fires and can cause other materials to burn without air.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  11. Q11.Division 5.2 materials are known as:

    A.Oxidizers
    B.Organic Peroxides
    C.Poison Gases
    D.Infectious Substances
    BOrganic Peroxides

    Explanation: Division 5.2 contains Organic Peroxides, which are thermally unstable and may burn rapidly or explode.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  12. Q12.Class 6 materials are divided into Poison/Toxic (6.1) and:

    A.Radioactive (6.2)
    B.Infectious Substances (6.2)
    C.Corrosive (6.2)
    D.Flammable Solid (6.2)
    BInfectious Substances (6.2)

    Explanation: Class 6 is divided into 6.1 (Poison/Toxic materials) and 6.2 (Infectious Substances/Biohazards).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  13. Q13.Potassium Cyanide is an example of:

    A.Division 6.1 (Poison)
    B.Class 8 (Corrosive)
    C.Class 9 (Miscellaneous)
    D.Division 2.3 (Poison Gas)
    ADivision 6.1 (Poison)

    Explanation: Potassium Cyanide is a toxic solid, falling under Division 6.1 Poison (Toxic) materials. (Division 2.3 is for gases).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  14. Q14.Hazard Class 7 includes:

    A.Corrosives
    B.Radioactive materials
    C.Miscellaneous hazmat
    D.Explosives
    BRadioactive materials

    Explanation: Class 7 consists of Radioactive materials (e.g., Uranium, medical isotopes).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  15. Q15.What is the primary hazard of Class 8 materials?

    A.They explode under pressure
    B.They burn skin and corrode metal
    C.They are radioactive
    D.They are infectious
    BThey burn skin and corrode metal

    Explanation: Class 8 Corrosives cause visible destruction or irreversible alterations to human skin or corrode metal (like aluminum/steel).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  16. Q16.Battery fluid (acid) is an example of:

    A.Class 3
    B.Class 6.1
    C.Class 8
    D.Class 9
    CClass 8

    Explanation: Battery acid is corrosive to skin and metal, placing it in Class 8.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  17. Q17.Class 9 materials are:

    A.Explosives
    B.Miscellaneous hazardous materials
    C.Gases
    D.Radioactive
    BMiscellaneous hazardous materials

    Explanation: Class 9 covers Miscellaneous hazardous materials that present a hazard during transport but do not meet the definition of any other class (e.g., dry ice, lithium batteries, asbestos).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  18. Q18.Which Division includes 'Consumer Commodities' (ORM-D)?

    A.Class 9
    B.Division 6.1
    C.It is a reclassification of certain materials for retail sale
    D.Class 1
    CIt is a reclassification of certain materials for retail sale

    Explanation: ORM-D (Other Regulated Material) is a reclassification for materials packaged for retail sale that pose limited hazard. (Note: ORM-D is being phased out for Limited Quantity, but still appears on some legacy exams).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  19. Q19.Division 2.3 covers:

    A.Flammable Gases
    B.Non-Flammable Gases
    C.Poison Gases
    D.Tear Gas
    CPoison Gases

    Explanation: Division 2.3 is Poison Gas (e.g., Chlorine, Phosgene), known to be toxic to humans.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  20. Q20.Which of the following is considered a 'Combustible Liquid'?

    A.A liquid with a flash point below 100°F
    B.A liquid with a flash point between 140°F (or 100°F depending on definition year) and 200°F
    C.A solid that burns
    D.A gas that burns
    BA liquid with a flash point between 140°F (or 100°F depending on definition year) and 200°F

    Explanation: Combustible liquids have higher flash points (typically >140°F or >100°F in older regs, but <200°F) than Flammable Liquids. Diesel fuel is a common combustible liquid.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  21. Q21.Which division of explosives contains items with a 'minor explosion' hazard (e.g., consumer fireworks)?

    A.1.1
    B.1.2
    C.1.3
    D.1.4
    D1.4

    Explanation: Division 1.4 consists of explosives that present a minor explosion hazard (e.g., small arms ammunition, consumer fireworks).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  22. Q22.A material that yields oxygen and causes combustion is a(n):

    A.Flammable Solid
    B.Oxidizer
    C.Corrosive
    D.Poison
    BOxidizer

    Explanation: This is the definition of an Oxidizer (Division 5.1).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  23. Q23.Helium is classified as:

    A.2.1 Flammable Gas
    B.2.2 Non-Flammable Gas
    C.2.3 Poison Gas
    D.Class 9
    B2.2 Non-Flammable Gas

    Explanation: Helium is an inert, non-flammable, non-poisonous compressed gas (Division 2.2).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  24. Q24.Division 6.2 'Infectious Substances' includes:

    A.Arsenic
    B.Medical waste, virus cultures, and diagnostic specimens
    C.Battery acid
    D.Tear gas
    BMedical waste, virus cultures, and diagnostic specimens

    Explanation: Division 6.2 includes materials known or reasonably expected to contain pathogens (bacteria, viruses, etc.).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  25. Q25.What is the difference between Division 1.1 and 1.2 explosives?

    A.1.1 is Mass Explosion; 1.2 is Projection Hazard
    B.1.1 is Fire Hazard; 1.2 is Mass Explosion
    C.1.1 is Minor Hazard; 1.2 is Mass Explosion
    D.There is no difference
    A1.1 is Mass Explosion; 1.2 is Projection Hazard

    Explanation: Division 1.1 has a mass explosion hazard (blast). Division 1.2 has a projection hazard (shrapnel/debris) but not a mass explosion hazard.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  26. Q26.Which class includes lithium batteries?

    A.Class 8
    B.Class 3
    C.Class 9
    D.Class 4.1
    CClass 9

    Explanation: Lithium batteries are classified as Class 9 Miscellaneous Hazardous Materials.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  27. Q27.What defines a 'Flammable Liquid' (Class 3)?

    A.A liquid with a flash point of not more than 60°C (140°F)
    B.A liquid that burns at any temperature
    C.A liquid with a flash point above 200°F
    D.A liquid that spontaneously combusts
    AA liquid with a flash point of not more than 60°C (140°F)

    Explanation: The DOT defines a Flammable Liquid as one having a flash point of not more than 60°C (140°F).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  28. Q28.Division 1.3 explosives have a primary hazard of:

    A.Mass explosion
    B.Fire and/or minor blast/projection
    C.Toxic gas
    D.Corrosion
    BFire and/or minor blast/projection

    Explanation: Division 1.3 explosives (like display fireworks) have a fire hazard and either a minor blast or minor projection hazard, but not a mass explosion hazard.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  29. Q29.Ammonium Nitrate is a common example of:

    A.Division 1.1
    B.Division 5.1 Oxidizer
    C.Class 8 Corrosive
    D.Class 3 Flammable Liquid
    BDivision 5.1 Oxidizer

    Explanation: Ammonium Nitrate is a powerful oxidizer (Division 5.1) used in fertilizers and explosives.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  30. Q30.Division 1.5 explosives are:

    A.Very sensitive
    B.Very insensitive substances with a mass explosion hazard
    C.Minor explosion hazard
    D.Not regulated
    BVery insensitive substances with a mass explosion hazard

    Explanation: Division 1.5 consists of Very Insensitive explosives (like blasting agents) that have a mass explosion hazard but are so insensitive that there is little probability of initiation during transport.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  31. Q31.Class 8 materials (Corrosives) can be:

    A.Liquids only
    B.Solids only
    C.Liquids or Solids
    D.Gases only
    CLiquids or Solids

    Explanation: Corrosives can be either liquids (like battery acid) or solids (like sodium hydroxide pellets).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  32. Q32.Dry Ice (Carbon Dioxide, solid) is classified as:

    A.Class 2.2
    B.Class 3
    C.Class 4.1
    D.Class 9
    DClass 9

    Explanation: Dry Ice is Class 9 (Miscellaneous) because it produces carbon dioxide gas which can displace oxygen in confined spaces.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  33. Q33.Which class is typically associated with the 'Spontaneously Combustible' placard?

    A.4.2
    B.4.1
    C.4.3
    D.5.1
    A4.2

    Explanation: Division 4.2 is Spontaneously Combustible.

    Join 1,000+ users passing the CDL Hazmat Endorsement

  34. Q34.An 'Inhalation Hazard' is most likely associated with:

    A.Division 2.3 (Poison Gas) or Division 6.1 (Poison Liquid)
    B.Class 3
    C.Class 9
    D.Division 1.4
    ADivision 2.3 (Poison Gas) or Division 6.1 (Poison Liquid)

    Explanation: Materials that are toxic by inhalation fall under Division 2.3 (gases) or Division 6.1 (liquids meeting inhalation toxicity criteria).

    Join 1,000+ users passing the CDL Hazmat Endorsement

  35. Q35.Division 1.6 explosives are:

    A.Extremely insensitive articles with no mass explosion hazard
    B.Mass explosion hazard
    C.Projection hazard
    D.Fire hazard
    AExtremely insensitive articles with no mass explosion hazard

    Explanation: Division 1.6 contains Extremely Insensitive Detonating Substances (EIDS) which demonstrate a negligible probability of accidental initiation or propagation.

    Join 1,000+ users passing the CDL Hazmat Endorsement

Want all 345 questions?

Download VoltExam — $17.99 Lifetime

Offline access, 345+ questions, built-in calculators. One-time unlock, no subscription.

Download on the App Store

More CDL Hazmat Endorsement Exam Topics